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| Carbon
Nanotubes: Fundamentals and Applications |
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Ed Wijaranakula, Ph.D.
Chief Technical Officer, Infotix
Systems, Inc. - June 21, 2004
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Since the
first report on
a discovery of helical graphitic
carbon microtubules in 1991 by NEC research
scientist Dr. Sumio
Iijima [1], carbon
nanotubes (CNTs) have received
a great deal
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of worldwide attention from government, academia and industry.
Because of its
ultra-light weight and superior material properties,
CNTs
are considered to
be one of the most promising novel materials
suitable for a
wide range of applications in nanotechnolgy from
nanoelectronics and bioengineering to biotechnology.
Two of the most common forms of carbon nanotubes are single-
and multi-wall. A single-walled nanotube (SWNT) consists
of carbon atoms that resemble rolled up sheets of
graphite, ~ 1.5 nm in diameter. Laboratory tests show
that a single-walled carbon nanotube has a mean tensile strength
as high as 30
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alloy used in aerospace applications. A multi-walled
nanotube (MWNT), with a sidewall consisting of five to
twenty carbon atom layers, are ~ 2 - 20 nm in diameter
and contain more structural defects than a SWNT.
Manufacturing Techniques - Several
techniques based upon similar principles of vaporization
and condensation of carbon are used in CNT manufacturing.
The least complicated technique
is the Carbon
Arc or Arc Discharge. In this technique, two graphite
electrode rods containing transition metal catalysts (Co
or Ni) are placed in a low-pressure chamber filled with an
inert gas (helium or argon). An electrical current (50A - 100A) between anode and cathode graphite rods
causes a high temperature discharge and vaporization of
the anode graphite rod. Vaporized carbon is condensed on
the cool chamber sidewall and forms nanotubes and
soot.
In laboratories such as the NASA Ames Research
Center [3], the purest
form of SWNTs can be produced at the rate of 0.3 to 0.4
grams per hour using the pulsed laser vaporization (PLV)
technique. In this technique, a carbon graphite target containing
~ 0.5 atomic percent of Co
and/or Ni as a catalyst is used. The target is
placed in a pressurized tube at elevated temperatures, ~
1200ºC and then ablated or evaporated using high-power Nd:YAG (Neodymium:
Yttrium-Aluminum-Garnet) lasers.
Carbon vapor is condensed on the cool wall collector in
the form of SWNTs. Large-scale production
of SWNTs can
be done using either a chemical
vapor deposition (CVD) [4] or "High-Pressure
CO conversion" (HiPCO) [5] techniques. In a chemical
vapor deposition (CVD) technique,
hydrocarbon gas flows through a transition metal
catalyst substrate in a reactor tube operated at temperatures between 600 and 1200ºC.
CNTs are formed directly on the substrate as
a result of the dissolution of hydrocarbon gas molecules
catalyzed by the transition metal at high temperatures.
This technique is highly suitable for nanoelectronics since
selective SWNTs can be grown on substrate using standard
microlithography processes. In the HiPCO technique, SWNTs are produced by flowing a
gas mix of CO with a small amount of iron pentacabonyl Fe(CO)5
catalytic particles, through high-pressured heated
carbon monoxide
(CO) gas in a quartz tube reactor,
operated at ~ 1200ºC. Because CO gas
is used as the primary gas source, CNTs produced by the
HiPCO technique contain no hydrocarbon and are considerably cleaner than
CNTs produced by the CVD technique.
Applications - Although small companies such as Chapel
Hill, N.C.-based Xintek,
have developed and commercialized carbon nanotube
materials, carbon nanotubes for cold cathodes, Atomic
Force Microscope (AFM) tips and x-ray tubes since 2000, most
products are still in the laboratory development stage.
In Japan, carbon nanotube-based cold cathodes, for
example, are being developed as field-emission
displays (FEDs) for future ultrahigh-definition
televisions.
Research scientists at Munich, Germany-based Infineon
Technologies AG (NYSE ADR: IFX) announced that they have
already successfully grown carbon nanotubes on a 150-mm
silicon wafer substrate using a selective CVD technique [6].
The company's first plan is to use the carbon nanotubes to
replace the conventional vias, the contact bridges between
two metal layers in the chip, and later all of the metal
layers with the CNT material.
Purdue
University researchers have shown that carbon nanotubes could
be used to create brain probes and implants to study and
treat neurological damage and disorders [7]. Probes made of
silicon that are currently used, cause the body to
produce scar tissue that eventually accumulates and prevents
the devices from making good electrical contact with brain
cells called neurons. |
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In
biomedical technology, particle Engineering Research Center (PERC)
researchers at the University of Florida have recently
developed a new alternative drug transport technology
consisting of tubular carbon nanotubes containing drug
payloads, which are sealed by carbon nanocaps [8]. The
researchers hope that one day these smart nanotubes would be
able to deliver drugs to only the target cells (diseased
cells), thereby greatly reducing the dose a patient would
need to take.
REFERENCES
[1]
S. Iijima, Nature, 354 (1991) 56-58.
[2] Min-Feng Yu, et al, Phys.
Rev. Lett. 84, 5552–5555 (2000).
[3] Center for
Nanotechnology, NASA Ames Research Center, 2004.
[4] N.R. Franklin, ed al, Advanced Materials, 12, June 2000.
[5] P. Nikolaev, et al,
Chem. Phys. Lett., 91, 313(1999).
[6] Semiconductor
International, Online, September 1, 2002.
[7] Purdue University, Press Release, January 7, 2004.
[8] University of Florida, Particle Engineering Research
Center, Press Release, March 24, 2004.
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About the Author: Dr. Ed Wijaranakula is presently the
Chief Technical Officer at Infotix Systems, Inc. Prior to Infotix Systems, he has worked with
Intel, Hewlett-Packard, Micron, Motorola and Texas Instruments and has held senior as well
as managerial positions in semiconductor manufacturing companies. He has published over 80
technical papers and holds more than 12 U.S. and foreign patents. His portfolio holds long
position
or control in IFX.
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